A)Explain, with the examples where possible, the following:
i)work (2mrks)
ii)heat (2mrks)
iii)Bohr Temperture (2mrks)
iv)Order of a reaction(2mrks)
v)reaction mechanism (2mrks)
B)i)Explain why real gases deviate from ideal gas behavior (3mrks)
ii)State the principle of corresponding states.(1mrk)
iii)Estimate the critical constants of a gas with van der waals paremeters a= 0.751 atm L2mol-2 and b=0.0226 Lmol-1(3mrks)
C(i)Explain what is internal energy (U).
(ii) A mole of monoatomic gas at 1 bar and 273.15K is allowed to expand adiabatically against a constant pressure of 0.395 bar until equilibrium (CV =3/2 R)
a)Calculate the final volume.(2mrks)
b) Calculate the final temperature.(2mrks)
c)calculate the work done during the process.(2mrks).
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